Polyacetylene Battery with Polymeric Solid Electrolyte
Polyacetylene Battery with Polymeric Solid Electrolyte
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聚合物固体电解质聚乙炔电池
DOI：
10.1143/jjap.24.l397
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发表时间：
1985
影响因子：
1.5
通讯作者：
O. Omoto
中科院分区：
文献类型：
--
作者：
T. Nagatomo;H. Kakehata;Chiaki Ichikawa;O. Omoto
以（CH）x薄膜为电极活性材料，PVDF·LiClO 4·PC（LiClO 4/PC in polyvinylidene fluoride，PVDF）薄膜为电解液，制备了可充全塑电池。(CH)x/PVDF·LiClO 4·PC/（CH）x电池表现出3.4 V的开路电压和10 mA的初始短路电流（两个电极;约10 mA）。8 mg，掺杂水平y=0.004）。该全塑料电池的最大功率密度为1.1kW/kg，能量密度为6.5Wh/kg（掺杂水平y=0.004，（CH）x电极的重量;约0.005）。8mg）。对该电池进行了50次充电-放电循环的研究，尽管掺杂水平较浅（y=0.001）。库仑效率为53%。
The rechargeable all-plastic battery was fabricated using the (CH)x film as the electrode active material and PVDF·LiClO4·PC (LiClO4/PC in polyvinylidene fluoride (PVDF)) film as the electrolyte. (CH)x/PVDF·LiClO4·PC/(CH)x battery exhibited an open-circuit voltage of 3.4 V and an initial short-circuit current of 10 mA (both electrodes; ca. 8 mg, doping level y=0.004). The maximum power density for this all-plastic battery was 1.1 kW/kg and an energy density of 6.5 Wh/kg (doping level y=0.004, weight of (CH)x electrodes; ca. 8 mg). This battery was investigated for 50 charge-discharge cycles, although doping levels were shallow (y=0.001). The coulombic efficiency was 53%.