A Crystallographic Study on the Growth of Partially Faceted MnSn2 Phase during Solidification Process

A Crystallographic Study on the Growth of Partially Faceted MnSn2 Phase during Solidification Process
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凝固过程中部分刻面MnSn2相生长的晶体学研究

DOI:
10.3390/cryst8100380
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发表时间:
2018-09
期刊:
影响因子:
2.7
通讯作者:
Cui Jianzhong
Cui Jianzhong
中科院分区:
材料科学3区
文献类型:
--
作者:
Li Lei;Bi Yuantong;Ban Chunyan;Zhang Haitao;Liu Tie;Wang Xiangjie;Esling Claude;Cui Jianzhong

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用结晶学方法研究了锡锰合金凝固过程中MnSn2相的生长。结果表明,MnSn2晶体的无向球帽沿晶向快速生长,遵循连续生长机制,侧面为二维形核机制,形成低折射率的{100}和{110}晶面。界面结构分析表明,{100}晶面间距周期(IPSP)内的原子面的平均网状密度低于{011}晶面间距周期内的平均网状结构密度。这导致了更快的生长速度,从而缩短和消失了{100}面。因此,部分刻面(即非刻面球帽和刻面侧面)的MnSn2晶体在三维上遵循八角底/球帽几何模型(很少有晶体具有正方形底面)。
The growth of MnSn2 phase during the solidification process of Sn-Mn alloy was crystallographically investigated. The results show that the non-faced spherical caps of the MnSn2 crystals follow the continuous growth mechanism to grow rapidly along the <001> direction, while the side surfaces the two-dimensional nucleation mechanism to form the low index {100} and {110} facets. An interface structure analysis indicates that the atom planes within the {100} interplanar spacing period (IPSP) has a lower average reticular density than those within the {011} IPSP. This leads to the faster growth rates and thus the shortening and disappearance of the {100} side facets. As a consequence, the partially faceted (i.e., non-faceted spherical caps and faceted side surfaces) MnSn2 crystals follow an octagonal-base/spherical-cap geometric model (few crystals possess square bases) in three dimensions.
DOI: 10.1016/0739-6260(91)90141-l
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