Surface study of the reconstructed anatase TiO_2 (001) surface
Surface study of the reconstructed anatase TiO_2 (001) surface
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DOI:
10.1016/j.pnsc.2020.11.002
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发表时间:
2021
期刊:
影响因子:
--
通讯作者:
Wang Yong
中科院分区:
文献类型:
--
作者:
Li Guanxing;Fang Ke;Ou Yang;Yuan Wentao;Yang Hangsheng;Zhang Ze;Wang Yong
The anatase TiO_2 (001) surface has attracted extensive attention in surface science and for practical applications because of its excellent performance.However,the highly reactive (001) surface usually reconstructs to a (1 × 4)-(001) surface,which may potentially alter its properties.As a result,there are still controversial issues concerning the intrinsic performance of this surface.Recently,significant advances have been made in the surface science study of TiO_2 (001),which have elucidated its intrinsic physical and chemical properties.In this review,we summarize our present understanding of the structure and properties of the reconstructed TiO_2 (001) surface.First,we provide a brief background of the anatase TiO_2 surfaces,including its low-index surface structures and the synthesis of anatase TiO_2 nanocrystals with the (001) surface exposed.Next,we focus on the structure,formation mechanism,stability,and surface chemistry of the reconstructed TiO_2 (001) surface.Finally,we finish this review by highlighting the current challenges of this subject and providing future research perspectives.