RANEY® Ni catalyzed transfer hydrogenation of levulinate esters to γ-valerolactone at room temperature.
RANEY® Ni catalyzed transfer hydrogenation of levulinate esters to γ-valerolactone at room temperature.
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DOI：
10.1039/c3cc40980e
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发表时间：
2013-05
影响因子：
4.9
通讯作者：
Zhen Yang;Yao-Bing Huang;Q. Guo;Yao Fu
中科院分区：
文献类型：
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作者：
Zhen Yang;Yao-Bing Huang;Q. Guo;Yao Fu
开发了室温下由乙酰丙酸乙酯（EL）和氢供体催化转移加氢生产γ-戊内酯（GVL）的工艺。乙酰丙酸乙酯几乎定量地转化为γ-戊内酯。此外，还报道了从生物质衍生的平台分子产生GVL的两步法。
A catalytic transfer hydrogenation process was developed for the production of γ-valerolactone (GVL) from ethyl levulinate (EL) and a H-donor at room temperature. Ethyl levulinate was almost quantitatively converted to γ-valerolactone. Further, a two step process for producing GVL from biomass derived platform molecules was also reported.