Design, Synthesis, and Application of Phosphaalkenes to Unique Palladium and Gold Catalysts

Design, Synthesis, and Application of Phosphaalkenes to Unique Palladium and Gold Catalysts
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DOI：
10.1080/10426500701764924
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发表时间：
2008-01
期刊：
Phosphorus, Sulfur, and Silicon and the Related Elements
影响因子：
--
通讯作者：
S. Ito;M. Freytag;Hongze Liang;Katsunori Nishide;M. Yoshifuji
S. Ito;M. Freytag;Hongze Liang;Katsunori Nishide;M. Yoshifuji
中科院分区：
其他
文献类型：
--
作者：
S. Ito;M. Freytag;Hongze Liang;Katsunori Nishide;M. Yoshifuji

文献摘要

相似文献

2-甲硅烷基-1,3-二磷丙烯被用作稳定钯(II)催化剂的不对称P2配体。利用几种磷烯配体合成新型金（I）配合物，该配合物在 1,6-烯炔环异构化中表现出独特的催化活性，表明 P = C 双键、Au-Au 接触和硫烷基的影响。
A 2-silyl-1,3-diphosphapropene was utilized as an asymmetrical P2 ligand of stable palladium(II) catalysts. Several phosphaalkene ligands were utilized for synthesis of novel gold(I) complexes which exhibited unique catalytic activity in 1,6-enyne cycloisomerization, indicating effects of P = C double bond, Au–Au contact, and sulfanyl group.