Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds
Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds
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DOI：
10.1039/c1dt10366k
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发表时间：
2011-08-01
影响因子：
4
通讯作者：
Rosenthal, Uwe
中科院分区：
文献类型：
--
作者：
Beweries, Torsten;Hansen, Sven;Rosenthal, Uwe
Me（2）NH中心点BH（3）（1）通过Cp（2）M（L）（eta（2）-Me（3）SiC（2）SiMe（3））[Cp = eta（5）-N; M = Ti，无L（2 Ti）; M = Zr，L =吡啶（2 Zr）]和M（NMe（2））（4）[M = Ti（8 Ti），Zr（8 Zr）]型四族金属氨基配合物。
Dehydrogenation of Me(2)NH center dot BH(3) (1) by group 4 metallocene alkyne complexes of the type Cp(2)M(L)(eta(2)-Me(3)SiC(2)SiMe(3)) [Cp = eta(5)-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe(2))(4) [M = Ti (8Ti), Zr (8Zr)] is presented.