POTENTIAL THEORY OF ADSORPTION
POTENTIAL THEORY OF ADSORPTION
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DOI：
10.1126/science.141.3585.1010
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发表时间：
1963-01-01
期刊：
影响因子：
56.9
通讯作者：
POLANYI, M
中科院分区：
文献类型：
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作者：
POLANYI, M
12.第二次实验于1963年8月23日进行。理论上。这一结果后来在我的学生和其他作者的一些论文中得到了证实。结果令人印象深刻。赫伯特·弗罗因德利希（Herbert Freundlich）是当时研究这个问题最权威的作家，他在1922年出版的《化学资本论》（Kapillarchemie）的下一版中对我的理论作了全面的阐述。他对我说：”我现在非常支持你的理论，我希望它是正确的。“其实，他的话已经表达了一种不安，很快我的理论就几乎被普遍否定了。怎么会这样？在这一理论诞生的那些年里，出现了一系列令人眼花缭乱的关于事物本质的见解。德拜的固定偶极子的发现，玻尔的原子模型，以及布拉格和W。L.布拉格，建立了电力在物质结构中的普遍作用。因此，似乎很明显，凝聚力必须用电的相互作用来解释。在这方面提出了许多理论。Keesom提出了固定四极子的静电相互作用; Debye提出了四极子与感应偶极子的相互作用。科塞尔将所有的化学键解释为正负离子之间的吸引力也属于这一时期。这种原子力的观点使我的吸附理论站不住脚。
12. A second experiment was performed on 23 August 1963. with th-theory. This result was confirmed later in a number of papers by my pupils and by other authors (2). The result was impressive. Herbert Freundlich, then the most authoritative writer on this subject, gave a full account of my theory in the next edition of his Kapillarchemie, published in 1922. He told me," I am heavily committed now to your theory myself; I hope it is correct." Actually, his words already expressed an uneasiness, and soon my theory was almost universally rejected. How did this happen? During the very years in which the theory was born, there occurreda daz-zling series of insights into the nature of things. Debye's discovery of fixed dipoles, Bohr's atomic model, and the ionic structure of sodium chloride found by WH Bragg and W. L. Bragg, established the pervasive function of electrical forces in the archi-tecture of matter. It seemed obvious that, in consequence, cohesive forces must be explained by electrical inter-action. A number oftheories were put forward on these lines. Keesom sug-gested an electrostatic interaction of fixed quadrupoles; Debye, an interaction of quadrupoles with induced dipoles. Kossel's attemptto explain all chemical bonds as attraction between positive and negative ions also belongs to this period. This view of atomic forces made my theory of adsorption untenable.