"Control of the Conformational Dynamics of meso-meso Vinylene-bridged Zn(II) Porphyrin Dimers through Diamine Coordination"
"Control of the Conformational Dynamics of meso-meso Vinylene-bridged Zn(II) Porphyrin Dimers through Diamine Coordination"
复制标题
“通过二胺配位控制内消旋-内消旋亚乙烯基桥接的锌（II）卟啉二聚体的构象动力学”
DOI：
10.1039/c4cc00126e
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发表时间：
2014
期刊：
影响因子：
--
通讯作者：
and D. Kim
中科院分区：
文献类型：
--
作者：
M. Son;Y. M. Sung;S. Tokuji;N. Fukui;H. Yorimitsu;A. Osuka;and D. Kim
两个meso-meso乙烯基桥联的锌（II）卟啉二聚体1和2进行了分析，在其周围的双键桥的旋转诱导的构象动力学的控制方面。通过与不同链长的α，ω-二氨基烷烃配位，调节了两个卟啉环之间的二面角。
Two meso–meso vinylene-bridged Zn(II) porphyrin dimers 1 and 2 were analyzed in terms of the control of their conformational dynamics induced by the rotation around the double bond bridge. The dihedral angles between the two porphyrin rings were modulated through coordination with α,ω-diaminoalkanes of varying chain lengths.