Infrared studies of carboxylic acids and pyridine in chloroform and methanol
Infrared studies of carboxylic acids and pyridine in chloroform and methanol
复制标题
氯仿和甲醇中羧酸和吡啶的红外研究
DOI：
10.1139/v78-421
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发表时间：
1978
影响因子：
1.1
通讯作者：
J. A. Gowland
中科院分区：
文献类型：
--
作者：
B. Dawa;J. A. Gowland
用红外光谱法研究了乙酸、氯乙酸和三氯乙酸与不同相对浓度吡啶在氯仿中的反应。同样的系统也在甲醇中进行了研究。一些不同的分配的峰，并解释了以前观察到的三氯乙酸在氯仿中的电荷转移络合物的形成方面的异常红外结果。
The reactions of acetic, chloroacetic, and trichloroacetic acids with varying relative concentrations of pyridine in chloroform have been reinvestigated using infrared spectroscopy. The same Systems have also been studied in methanol. Some different assignments of peaks have been made, and the anomalous infrared results previously observed for trichloroacetic acid in chloroform are explained in terms of charge transfer complex formation.