Repulsion of syn-axial electron pairs. The rabbit-ear effect
Repulsion of syn-axial electron pairs. The rabbit-ear effect
复制标题
同轴电子对的排斥。
DOI：
10.1021/ja01027a078
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发表时间：
1968
影响因子：
15
通讯作者：
E. Eliel
中科院分区：
文献类型：
--
作者：
R. O. Hutchins;L. Kopp;E. Eliel
0.02 M-1 sec-1. Ill was isolated and kept as a yellow solid at—196; upon warming decomposition to methane and nitrogen began. We were unable to es-tablish a simple kinetic order for the gas-phase decom-position of III. The half-life decreased as the partial pressure of III was decreased, eg, n/t~ 2 min at 82 mm which increased to~ 8 min at 10 mm at a total pressure of~ 400 mm. IV had an appreciably longer half-life.Diazene itself decomposes so rapidly that it has only recently been observed in some detail. 4 As the simplest substituted diazene of reasonable stability yet re-ported, methyldiazene is of considerable chemical interest. We have made the extension of the preparative method to obtain ethyldiazene by substituting N-ethylhydroxylamine in reaction 1.
