STRUCTURE AND INTERMOLECULAR INTERACTION IN LIQUID-CRYSTALLINE MIXED PHASES - PROGRESS REPORT

STRUCTURE AND INTERMOLECULAR INTERACTION IN LIQUID-CRYSTALLINE MIXED PHASES - PROGRESS REPORT
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DOI:
10.1002/bbpc.19930971023
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发表时间:
1993-10-01
期刊:
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS
影响因子:
--
通讯作者:
DIELE, S
DIELE, S
中科院分区:
其他
文献类型:
--
作者:
DIELE, S

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在棒状、柱状和聚合物系统的二元混合物中讨论了特定分子间相互作用(偶极子、EDA、空间相互作用以及氢键)的例子。结果表明,在液晶态完全混溶的基础上,分子间相互作用根据浓度实现连续变化。通过这种方式,混合适当的第二组分可以明确地影响混合物的性质。
Examples of specific intermolecular interaction (dipole, EDA, steric interactions as well as hydrogen bonds) are discussed in binary mixtures of calamitic, columnar and polymeric systems. It is shown, that on the base of the complete miscibility in the liquid crystalline state a continuous change of the intermolecular interaction is achieved in dependence on the concentration. In this way the properties of the mixtures can be definitively influenced by admixing of a proper second component.