Strong cation···π interactions promote the capture of metal ions within metal-seamed nanocapsule.

Strong cation···π interactions promote the capture of metal ions within metal-seamed nanocapsule.
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DOI:
10.1021/ja5107354
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发表时间:
2014-12-10
影响因子:
15
通讯作者:
Atwood, Jerry L.
Atwood, Jerry L.
中科院分区:
化学1区
文献类型:
--
作者:
Kumari, Harshita;Jin, Ping;Teat, Simon J.;Barnes, Charles L.;Dalgarno, Scott J.;Atwood, Jerry L.

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铊离子被输送到镓缝邻苯三酚[4]芳烃纳米胶囊的内部。Cs离子的捕获程度取决于铯盐中阴离子的类型和位置,相比之下,Tl··π与Cs··π相互作用强度的增强有助于Tl+离子在胶囊内部的永久捕获。用叔金属(Zn, Rb或K)“缝合”胶囊缝,可以获得新的固态三金属纳米胶囊。
Thallium ions are transported to the interior of gallium-seamed pyrogallol[4]arene nanocapsules. In comparison to the capture of Cs ions, the extent of which depends on the type and position of the anion employed in the cesium salt, the enhanced strength of Tl···π vs Cs···π interactions facilitates permanent entrapment of Tl+ ions on the capsule interior. “Stitching-up” the capsule seam with a tertiary metal (Zn, Rb, or K) affords new trimetallic nanocapsules in solid state.
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