Guanidines as a nitrogen source for direct conversion of epoxides to aziridines.

Guanidines as a nitrogen source for direct conversion of epoxides to aziridines.
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DOI：
10.1002/chin.200517110
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发表时间：
2004-10
期刊：
The Journal of organic chemistry
影响因子：
--
通讯作者：
Y. Tsuchiya;Takuya Kumamoto;T. Ishikawa
Y. Tsuchiya;Takuya Kumamoto;T. Ishikawa
中科院分区：
其他
文献类型：
--
作者：
Y. Tsuchiya;Takuya Kumamoto;T. Ishikawa

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环氧化物直接转化为氮杂环丙烷实现与胍作为氮源。在不损失光学纯度的情况下，观察到环氧化物手性中心的立体化学反转。
Direct conversion of epoxides to aziridines was achieved with guanidines as a nitrogen source. Stereochemical inversion at the chiral centers of epoxides was observed without loss of optical purity.