Barton-Zard pyrrole synthesis and its application to synthesis of porphyrins, polypyrroles, and dipyrromethene dyes
Barton-Zard pyrrole synthesis and its application to synthesis of porphyrins, polypyrroles, and dipyrromethene dyes
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DOI：
10.3987/rev-07-622
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发表时间：
2008-02
期刊：
影响因子：
0.6
通讯作者：
N. Ono
中科院分区：
文献类型：
--
作者：
N. Ono
通过异氰基乙酸烷基酯与硝基烯烃或乙烯基砜的反应（Barton-Zard反应，BZ反应）制备的吡咯可用于合成生物活性吡咯、卟啉、聚吡咯和二吡咯亚甲基染料。本文综述了BZ反应的最新进展及其在材料科学中的应用。
Pyrroles prepared by the reaction of alkyl isocyanoacetates with nitroalkenes or vinylsulfones (Barton-Zard reaction, BZ reaction) are useful for the synthesis of biologically active pyrroles, porphyrins, polypyrroles, and dipyrromethene dyes. This review covers recent development of the BZ reaction and its application to the field of material science.