Organotellurium-mediated controlled/living radical polymerization initiated by direct C-Te bond photolysis.
Organotellurium-mediated controlled/living radical polymerization initiated by direct C-Te bond photolysis.
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DOI：
10.1021/ja8099689
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发表时间：
2009-01
影响因子：
15
通讯作者：
S. Yamago;Yuu Ukai;A. Matsumoto;Yasuyuki Nakamura
中科院分区：
文献类型：
--
作者：
S. Yamago;Yuu Ukai;A. Matsumoto;Yasuyuki Nakamura
在乙烯基单体的存在下，有机碲链转移剂的紫外-可见光照射导致形成具有预定数均分子量和窄分子量分布的高度受控的活性聚合物。
UV-vis irradiation of an organotellurium chain transfer agent in the presence of vinyl monomers leads to the formation of highly controlled living polymers with predetermined number average molecular weights and narrow molecular weight distributions.