Evaluation of Strontium Doped Lanthanum Chromium Manganite (LSCM) and Gadolinium Doped Ceria (GDC) Anode with Different Compositions

Evaluation of Strontium Doped Lanthanum Chromium Manganite (LSCM) and Gadolinium Doped Ceria (GDC) Anode with Different Compositions
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不同成分的锶掺杂镧铬锰酸盐(LSCM)和钆掺杂氧化铈(GDC)阳极的评价

DOI:
10.1149/09101.1711ecst
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发表时间:
2019
期刊:
ECS Transactions
影响因子:
--
通讯作者:
N. Shikazono
N. Shikazono
中科院分区:
--
文献类型:
--
作者:
A. Sciazko;R. Yokoi;Y. Komatsu;Takaaki Shimura;N. Shikazono

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La0。9 sr0。1 cr0。5 mn0。5O3-δ (LSCM)和Gd0。1 ce0。对9O2-δ (GDC)粉末进行了评价。优化了烧结温度、电极厚度和成分。GDC占比大于70%的阳极初始极化电阻最低。然而,GDC份额超过80%的阳极在加速降解试验中明显降解。降解的原因是GDC相的纳米裂解。结果表明,LSCM具有稳定GDC结构的作用,LSCM-GDC 30:70 wt。考虑到初始性能和稳定性,发现%为最佳组成。
La0. 9Sr0. 1Cr0. 5Mn0. 5O3-δ (LSCM) and Gd0. 1Ce0. 9O2-δ (GDC) powders is evaluated. The sintering temperature, electrode thickness and composition are optimized. The anodes with GDC share over 70% exhibited the lowest initial polarization resistance. However, anodes with share of GDC over 80% significantly degraded in the accelerated degradation test. The reason of the degradation is attributed to the nano-cracking of the GDC phase. It was found out that LSCM stabilizes the GDC structure, and LSCM-GDC 30: 70wt.% was found to be the optimal composition considering the initial performance and stability.