Enzyme-based bilayer conducting polymer electrodes consisting of polymetallophthalocyanines and polypyrrole-glucose oxidase thin films.
Enzyme-based bilayer conducting polymer electrodes consisting of polymetallophthalocyanines and polypyrrole-glucose oxidase thin films.
复制标题
DOI：
10.1021/ac00034a008
复制
发表时间：
1992-05
影响因子：
7.4
通讯作者：
Z. Sun;H. Tachikawa
中科院分区：
文献类型：
--
作者：
Z. Sun;H. Tachikawa
采用电化学沉积法在玻碳电极上制备了由聚金属酞菁（PMePc）和聚吡咯葡萄糖氧化酶（PPy-GOx）组成的双层导电聚合物电极。双层膜电极表现出催化行为，其中包括增强的安培响应电流与基板和显着移动的氧化电位（约700 mV）的响应电流。双层电极也表现出快速的响应时间和良好的稳定性与基板。同时使用PCuPc和PPy-GOx聚合物膜制备的双层微电极也显示出良好的安培响应。
Bilayer conducting polymer electrodes, which consist of a polymetallophthalocyanine (PMePc) and polypyrrole incorporating glucose oxidase (PPy-GOx), were prepared on the glassy-carbon electrode by the successive electrochemical deposition of two different polymers. The bilayer film electrodes showed catalytic behavior, which included an enhanced amperometric response current with the substrate and a significantly shifted oxidation potential (approximately 700 mV) of the response current. The bilayer electrodes also showed a fast response time and good stability with the substrate. A bilayer microelectrode, which was prepared by using both PCuPc and PPy-GOx polymer films, also showed a good amperometric response with the substrate.