Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo)
Steric demand of the Cp*Ga ligand: Synthesis and structure of Ni(Cp*Ga)(4) and of cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo)
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Cp*Ga 配体的空间需求：Ni(Cp*Ga)(4) 和 cis-M(Cp*Ga)(2)(CO)(4) (M = Cr, Mo) 的合成和结构
DOI：
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发表时间：
1999
期刊：
影响因子：
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通讯作者：
H. Stammler
中科院分区：
文献类型：
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作者：
P. Jutzi;B. Neumann;Lars Oliver Schebaum;A. Stammler;H. Stammler
在（η5-五甲基环戊二烯基）镓（Cp*Ga）与Ni（COD）_2（COD = 1，5-环戊二烯基）和NorM（CO）_4（Nor =降冰片二烯; M = Cr，Mo）反应中，分别得到了配合物Ni（Cp*Ga）_4（1）和cis-M（Cp*Ga）_2（CO）_4（M = Cr（2），Mo（3））。化合物1 - 3通过NMR和IR数据以及元素分析表征。此外，对配合物1和3进行X射线晶体结构分析。Cp*Ga配体的顺式取向是通过Cp* 质心−Ga−M向量偏离线性而实现的。1是第一个以Cp*Ga为配体的均配型配合物。
In the reaction of (η5-pentamethylcyclopentadienyl)gallium (Cp*Ga) with Ni(COD)2 (COD = 1,5-cyclooctadiene) and NorM(CO)4 (Nor = norbornadiene; M = Cr, Mo) the complexes Ni(Cp*Ga)4 (1) and cis-M(Cp*Ga)2(CO)4 (M = Cr (2), Mo (3)), respectively, were obtained. Compounds 1−3 were characterized by NMR and IR data and by elemental analysis. In addition, an X-ray crystal structure analysis was performed on complexes 1 and 3. Cis-orientation of the Cp*Ga ligands is made possible by deviation of the Cp*centroid−Ga−M vector from linearity. 1 is the first homoleptic complex with Cp*Ga as ligand.