Polyoxometalate Chemistry - Some Recent Trends
Polyoxometalate Chemistry - Some Recent Trends
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多金属氧酸盐化学 - 一些最新趋势
DOI：
10.1142/9789814458986_0003
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发表时间：
2013
期刊：
影响因子：
--
通讯作者：
BOULAY A
中科院分区：
文献类型：
--
作者：
BOULAY A
Polyoxometalates (POMs) are discrete, anionic metal-oxide clusters of early transition metals. Composed principally of Mo, W, V and Nb, they represent a large and important class of inorganic molecules and materials, 1 whose relevance is being highlighted in a number of review articles, with an extraordinary reach in terms of applications, physical and chemical properties. 2, 3 One of the most interesting aspects of POM chemistry is the underlying deceptively simple synthetic procedures. 4 Indeed, the overwhelming majority of the POMs isolated and reported to date in the literature are formed using straightforward “one pot” and one step conditions. Frequently, in this “one-pot” process, acidification of the precursor metal salts in aqueous solutions in the presence of chosen ingredients such as reducing agents, hetero-elements, counterions etc. leads to the formation of a variety of combinatorially linkable polyoxometalate building blocks in solution. 5 These small building blocks, formed by the edge-and corner-sharing of {MOx} units (where M= Mo, W; x= 4–7),
