Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes
Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes
复制标题
卡宾和膦配体对金配合物催化炔烃氢胺化和氢肼化反应活性的影响
DOI：
10.1021/acscatal.0c01352
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发表时间：
2020-03
期刊：
影响因子：
12.9
通讯作者：
S. Yazdani;Glen P. Junor;Jesse L. Peltier;M. Gembicky;Rodolphe Jazzar;D. Grotjahn;G. Bertrand
中科院分区：
文献类型：
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作者：
S. Yazdani;Glen P. Junor;Jesse L. Peltier;M. Gembicky;Rodolphe Jazzar;D. Grotjahn;G. Bertrand
通过动力学测量、催化和化学计量实验以及密度泛函理论计算，比较了不同配体（R3P、NHC、NH4）负载的金配合物的催化活性。
Through kinetic measurements, catalytic and stoi-chiometric experiments, as well as DFT calculations, we compare the catalytic activity of gold complexes supported by a variety of ligands (R3P, NHC...