Recent advances in multidimensional ultrafast spectroscopy.

Recent advances in multidimensional ultrafast spectroscopy.
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DOI:
10.1098/rsos.171425
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发表时间:
2018-01
影响因子:
3.5
通讯作者:
Oliver TAA
Oliver TAA
中科院分区:
综合性期刊3区
文献类型:
--
作者:
Oliver TAA

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多维超快光谱是研究生物、化学和功能纳米材料系统凝聚相动力学的首要工具之一。随着它们的成熟,可以探索的频域的多样性大大增加,实验技术能够将从太赫兹到紫外线的激发和发射频率相关联。一些最新的创新还包括极端交叉峰光谱,直接关联电子和振动状态的动力学。本文综述了使这些最新进展得以实现的关键技术进展,以及从新的多维光谱探针中获得的见解。
Multidimensional ultrafast spectroscopies are one of the premier tools to investigate condensed phase dynamics of biological, chemical and functional nanomaterial systems. As they reach maturity, the variety of frequency domains that can be explored has vastly increased, with experimental techniques capable of correlating excitation and emission frequencies from the terahertz through to the ultraviolet. Some of the most recent innovations also include extreme cross-peak spectroscopies that directly correlate the dynamics of electronic and vibrational states. This review article summarizes the key technological advances that have permitted these recent advances, and the insights gained from new multidimensional spectroscopic probes.
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