Chromatographic Resolution of Racemates. New analytical methods (17)
Chromatographic Resolution of Racemates. New analytical methods (17)
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外消旋体的色谱分离。
DOI：
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发表时间：
1980
期刊：
影响因子：
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通讯作者：
G. Blaschke
中科院分区：
文献类型：
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作者：
G. Blaschke
许多外消旋体可以通过色谱法在光学活性吸附剂上拆分成光学纯的对映体。具有光学活性酰胺、氨基酸和冠醚基团的合成聚合物、天然产物如淀粉和纤维素以及微晶三乙酰基纤维素适用于此目的。外消旋体也可以通过气相色谱法在光学活性固定相上拆分。
A number of racemates can be resolved into optically pure enantiomers by chromatography on optically active adsorbents. Synthetic polymers with optically active amide, amino acid, and crown ether groups, natural products such as starch and cellulose, and also microcrystalline triacetylcellulose are suitable for this purpose. Racemates can also be resolved by gas chromatography on optically active stationary phases.