Polyimides: Promising Energy-Storage Materials
Polyimides: Promising Energy-Storage Materials
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聚酰亚胺：有前途的储能材料
DOI：
10.1002/anie.201002439
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发表时间：
2010-01-01
影响因子：
16.6
通讯作者：
Zhou, Yunhong
中科院分区：
文献类型：
--
作者：
Song, Zhiping;Zhan, Hui;Zhou, Yunhong
清洁和可持续的能源供应对人类的未来至关重要，因此是21世纪的关键问题。在能量转换和存储方面，锂电池在过去20年中发挥了不可或缺的作用，并且由于其在能量密度和可循环性方面的优势，在可预见的未来仍将如此。如今，锂电池市场，特别是考虑到电动汽车的发展，迅速增长，现在敦促科学家们不仅要关注能量密度，还要关注功率密度、安全性和可持续性。最近，Armand， Tarascon等人提出了“可持续电池”或“绿色电池”的概念[1-5]，旨在引起研究人员对大规模生产和使用基于常规无机电极的锂电池可能造成的资源问题和环境问题的关注。“可持续锂离子电池”的关键技术是开发可再生有机电极，这种电极最终可能由生物质合成。事实上，有机电极材料的概念并不新鲜。早在20世纪60年代，人们就开始研究二氯异氰尿酸作为锂电池的正极材料一些导电聚合物如聚苯胺、聚吡咯等已实现商业化然而，相对于有机材料在发光二极管（led）、光伏（PV）器件、场效应晶体管（fet）等领域的应用，用于可充电锂电池的有机电极材料的开发还远远落后。在20世纪80年代和90年代，人们开始寻找有机多硫化物阴极材料然而，由于其电化学性能差，稳定性不高，2000年后，这方面的研究减少了。最近，研究人员将他们的兴趣转向了基于羰基的有机材料，如酸酐和醌，并取得了
A clean and sustainable energy supply is essential for the future of human beings and is thus a crucial issue in the 21st century. Regarding energy conversion and storage, lithium batteries have played an indispensable role over the past 20 years and will do so for the foreseeable future because of their advantages in energy density and cyclability. Nowadays, the lithium battery market, especially given the development of electric automobiles, has grown rapidly, and scientists are now urged to focus on not only energy density, but also power density, safety, and sustainability. Recently, Armand, Tarascon, and co-workers introduced the concept of a “sustainable battery” or “green battery”,[1–5] aiming to evoke researchers concern over the resource issues and environmental issues that may be caused by large-scale production and use of Liion batteries based on conventional inorganic electrodes. The key technique for a “sustainable Li-ion battery” is to develop renewable organic electrodes, which may eventually be synthesized from biomass.In fact, the concept of an organic electrode material is not new. Dichloroisocyanuric acid was studied as a cathode material for a lithium battery as early as the 1960s.[6] Some conducting polymers such as polyaniline and polypyrrole have already been commercialized.[7] However, relative to the application of organic materials in the field of light-emitting diodes (LEDs), photovoltaic (PV) devices, and field-effect transistors (FETs),[8] the development of organic electrode materials for rechargeable lithium batteries lags far behind. In the 1980s and 1990s, there was a search for organic polysulfide cathode materials.[7] However, this research diminished after 2000, because of their poor electrochemical performance and low stability. Recently, researchers have shifted their interest toward organic materials based on the carbonyl group, such as anhydrides and quinones, and achieved