One-pot multi-step reactions based on thiolactone chemistry: A powerful synthetic tool in polymer science
One-pot multi-step reactions based on thiolactone chemistry: A powerful synthetic tool in polymer science
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DOI：
10.1016/j.eurpolymj.2014.07.008
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发表时间：
2015-01-01
影响因子：
6
通讯作者：
Du Prez, Filip E.
中科院分区：
文献类型：
--
作者：
Espeel, Pieter;Du Prez, Filip E.
基于硫代内酯化学的一锅多步反应作为一种强有力的工具出现，以一锅和优雅的方式制备定制的多官能化聚合物结构。这篇专题文章重点介绍了这种方法的最重要特征，这些特征在各种反应体系中得到了证明，包括（生物基）线性聚合物、杂遥爪聚合物、聚合物网络和非均相支持物。这一概述清楚地揭示了其显着的多功能性，涉及模块化合成和双重改性的聚合物：硫代内酯可以打开各种各样的功能胺和释放的硫醇可以与硫醇“清除剂”的选择反应。(C)2014爱思唯尔有限公司版权所有。
One-pot multi-step reactions based on thiolactone chemistry emerged as a powerful tool to prepare tailor-made, multi-functionalized polymer architectures in a one-pot and elegant manner. This feature article highlights the most important features of this approach, demonstrated in various reactive systems including (bio-based) linear polymers, heterotelechelic polymers, polymeric networks and heterogeneous supports. This overview clearly reveals its remarkable versatility involving modular synthesis and double modification of polymers: thiolactones can be opened by a wide variety of functional amines and the released thiol can react with thiol 'scavengers' of choice. (C) 2014 Elsevier Ltd. All rights reserved.