Decarboxylative Polymerization of 2,6-Naphthalenedicarboxylic Acid at Surfaces
Decarboxylative Polymerization of 2,6-Naphthalenedicarboxylic Acid at Surfaces
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DOI：
10.1021/ja5033875
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发表时间：
2014-07-09
影响因子：
15
通讯作者：
Fuchs, Harald
中科院分区：
文献类型：
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作者：
Gao, Hong-Ying;Held, Philipp Alexander;Fuchs, Harald
报道了2，6-萘二甲酸(NDCA)在不同表面上的金属催化聚合反应。聚合是通过自组装的二元酸的初始形式脱氢和随后的脱羧基来进行的，从而在高温下得到聚合的双萘基-铜物种作为中间结构(
Metal-catalyzed polymerization of 2,6-naphthalenedicarboxylic acid (NDCA) to form poly-2,6-naphthalenes at various surfaces is reported. Polymerizations occur via initial formal dehydrogenation of self-assembled diacids with subsequent decarboxylation to give polymeric bisnaphthyl-Cu species at elevated temperature as intermediate structures (