Ceria-Catalyzed Conversion of Carbon Dioxide into Dimethyl Carbonate with 2-Cyanopyridine
Ceria-Catalyzed Conversion of Carbon Dioxide into Dimethyl Carbonate with 2-Cyanopyridine
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DOI：
10.1002/cssc.201300229
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发表时间：
2013-08-01
期刊：
影响因子：
8.4
通讯作者：
Tomishige, Keiichi
中科院分区：
文献类型：
--
作者：
Honda, Masayoshi;Tamura, Masazumi;Tomishige, Keiichi
DMC RUN：在CeO2催化下，以2-氰基吡啶为脱水剂的反应体系中，二氧化碳可以转化为碳酸二甲酯。在Na2O/SiO_2催化剂上可实现副产物2-吡啶甲酰胺的再生。总体而言，该系统支持二氧化碳与甲醇反应生成碳酸二甲酯。
DMC run: Carbon dioxide can be converted into dimethyl carbonate in a reaction system involving 2‐cyanopyridine as a dehydration agent, catalyzed by CeO2. Regeneration of the coproduct 2‐picolinamide can be achieved over a Na2O/SiO2 catalyst. As a whole, the system servest to react carbon dioxide with methanol to produce dimethyl carbonate.