Catalytic [2 + 2 + 2] Cycloaddition Polymerization of Diyne-Nitrile Monomers in the Presence of CoCl2-6H2O/Diphosphine/Zn
Catalytic [2 + 2 + 2] Cycloaddition Polymerization of Diyne-Nitrile Monomers in the Presence of CoCl2-6H2O/Diphosphine/Zn
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CoCl2-6H2O/二膦/Zn 下二炔腈单体的催化[2 2 2]环加成聚合
DOI：
10.1002/pola.27780
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发表时间：
2016
期刊：
影响因子：
--
通讯作者：
Sentaro Okamoto
中科院分区：
文献类型：
--
作者：
Yu-ki Sugiyama;Sentaro Okamoto
钴催化的1，6-二炔和腈的[2 + 2 + 2]共环加成反应生成取代吡啶已被应用于二炔-腈单体的聚合，其反应以逐步生长的方式顺利进行，以提供主链中包含吡啶结构的线性聚合物。© 2015 Wiley Periodicals，Inc. J.波利姆科学，A部分：聚合物Chem.2016，54，345-351
Cobalt‐catalyzed [2 + 2 + 2] cocycloaddition reaction of 1,6‐diynes and nitriles to generate substituted pyridines has been applied to the polymerization of diyne–nitrile monomers, the reaction of which proceeded smoothly in a step‐growth fashion to provide linear polymers comprising pyridine structures in the main chain. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem.2016,54, 345–351