A highly water-soluble dendro[60]fullerene
A highly water-soluble dendro[60]fullerene
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DOI：
10.1016/s0040-4039(98)00491-2
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发表时间：
1998-04-30
影响因子：
1.8
通讯作者：
Hirsch, A
中科院分区：
文献类型：
--
作者：
Brettreich, M;Hirsch, A
C-60与第二代双（聚酰胺）-丙二酸酯树枝状聚合物的亲核环丙烷化和随后的末端叔丁基基团的脱保护提供了在外围具有18个羧基的树枝状[60]富勒烯。C-60的这种树枝状单加合物是高度水溶性的。(C)1998由Elsevier Science Ltd.出版。保留所有权利。
The nucleophilic cyclopropanation of C-60 With a second generation bis(polyamide)-malonate dendrimer and the subsequent deprotection of the terminal t-butyl groups provides a dendro[60]fullerene with 18 carboxylic groups in the periphery. This dendritic monoadduct of C-60 is highly water-soluble. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.