Taming a functional group:: Creating air-stable, chiral primary phosphanes
Taming a functional group:: Creating air-stable, chiral primary phosphanes
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DOI：
10.1002/anie.200602143
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发表时间：
2006-01-01
影响因子：
16.6
通讯作者：
Gilheany, Declan G.
中科院分区：
文献类型：
--
作者：
Hiney, Rachel M.;Higham, Lee J.;Gilheany, Declan G.
没有火环！对映纯伯膦在固体和溶液状态下对空气氧化都非常稳定（见例子）。这类新的稳定配体合成体的稳定性似乎归功于其芳基骨架与扩展的it环系统的结合。哪怕多一枚戒指也足够了。(图)。©2006 Wiley-VCH Verlag GmbH & Co. KGaA。
No rings of fire! Enantiopure primary phosphanes have been developed which are remarkably stable to air oxidation in both solid and solution states (see example). This new class of stable ligand synthon appears to owe its stability to conjugation in their aryl backbones with the extended it ring system. Even one extra ring is good enough.(Figure Presented).© 2006 Wiley-VCH Verlag GmbH & Co. KGaA.