Self-assembling Properties of (Arylimido)vanadium(V) Compounds
Self-assembling Properties of (Arylimido)vanadium(V) Compounds
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(芳基酰亚氨基)钒(V)化合物的自组装性能
DOI：
10.1016/j.ccr.2011.01.055
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发表时间：
2011
影响因子：
20.6
通讯作者：
Toshiyuki Moriuchi
中科院分区：
文献类型：
--
作者：
近藤輝幸;他;Toshiyuki Moriuchi
（亚氨基）钒（V）配合物因其作为催化剂的潜在应用而引起广泛关注。与氧代配体相比，亚氨基配体可以在亚氨基氮上具有取代基，因此金属中心的空间和电子性质被认为由氮取代基的性质控制。在这个意义上，设计的亚氨基配体被认为是一个关键因素，在开发有效的催化剂。此外，过渡金属定向组装以产生有组织的纳米结构的结构控制对于先进材料是重要的。本文综述了芳酰亚胺钒化合物的自组装性质。
(Imido)vanadium(V) complexes have attracted much attention because of their potential applications as catalysts. Compared with oxo ligands, imido ligands can possess a substituent on the imido nitrogen so that the steric and electronic characters of the metal center are considered to be controlled by the properties of the nitrogen substituent. In such a sense, the design of the imido ligands is envisioned to be one of the key factors in the development of efficient catalysts. Furthermore, architectural control of transition metal-directed assembly to create organized nanostructures is of importance for advanced materials. This review highlights self-assembling properties of (arylimido)vanadium(V) compounds.