Friedel-Crafts acylation and related reactions catalysed by heteropoly acids
Friedel-Crafts acylation and related reactions catalysed by heteropoly acids
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DOI：
10.1016/s0926-860x(03)00406-x
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发表时间：
2003-12-30
影响因子：
5.5
通讯作者：
Kozhevnikov, IV
中科院分区：
文献类型：
--
作者：
Kozhevnikov, IV
综述了近年来杂多酸（HPA）催化芳烃傅-克酰基化反应和芳香酯傅-克重排反应的研究进展。结果表明，HPA基固体酸是这些反应的高效和环境友好的催化剂，通常在活性上上级传统的酸催化剂，如H2SO 4或沸石。(C)2003 Elsevier B. V.保留所有权利。
Recent studies on catalysis by heteropoly acids (HPA) for the Friedel-Crafts acylation of arenes and related Fries rearrangement of aryl esters are reviewed. It is demonstrated that HPA-based solid acids are efficient and environmentally friendly catalysts for these reactions, usually superior in activity to the conventional acid catalysts such as H2SO4 or zeolites. (C) 2003 Elsevier B.V. All rights reserved.