Chemical Sodiation of V2O5 by Na2S
Chemical Sodiation of V2O5 by Na2S
复制标题
Na2S 对 V2O5 的化学钠化
DOI:
10.1002/zaac.201400381
复制
发表时间:
2014
期刊:
影响因子:
--
通讯作者:
Guido Kickelbick
中科院分区:
文献类型:
--
作者:
Robert Haberkorn;Jessica Bauer;Guido Kickelbick
Chemical sodiation of V2O5at low temperatures allows to synthesize NaxV2O5with 0 ≤x≤ 1, while classic high temperature syntheses yield in eitherx≤ 0.02 (α‐phase) or 0.7 ≤x(α′‐phase), or other phases (β‐phase, δ‐phase) or mixtures thereof. A suspension of V2O5in acetonitrile and Na2S as sodiation agent were used. The maximum amount of sodiation was obtained by using an excess of Na2S, refluxing the acetonitrile during the reaction, and precedent ball milling of the V2O5. If only low amounts of Na2S were used as starting material, a mixture of fractions of NaxV2O5with different values ofxwas obtained. All these fractions belong to the α‐ or α′‐phase, space groupPmmn.
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影响因子:
3.2
作者:
G. Pistoia;S. Panero;M. Tocci;R. Moshtev;V. Manev
通讯作者:
G. Pistoia;S. Panero;M. Tocci;R. Moshtev;V. Manev
影响因子:
2.4
作者:
H. Bak;Jae Ha Lee;Bok Ki Kim;W. Yoon
通讯作者:
W. Yoon
DOI:
10.1002/zaac.201300376
发表时间:
2014
期刊:
Zeitschrift für anorganische und allgemeine Chemie
影响因子:
--
作者:
O. Clemens;R. Haberkorn;M. Springborg;H. Beck
通讯作者:
H. Beck
影响因子:
--
作者:
S. Ng;N. Tran;K. Bramnik;H. Hibst;P. Novák
通讯作者:
P. Novák
DOI:
10.1107/s0108270198004855
发表时间:
1998
期刊:
Acta Crystallographica Section C-crystal Structure Communications
影响因子:
--
作者:
A. Meetsma;J. Boer;A. Damascelli;J. Jegoudez;A. Revcolevschi;T. Groningen;U. Paris
通讯作者:
U. Paris