Nucleophilicities and carbon basicities of DBU and DBN
Nucleophilicities and carbon basicities of DBU and DBN
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DOI：
10.1039/b801811a
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发表时间：
2008-04-21
影响因子：
4.9
通讯作者：
Mayr, Herbert
中科院分区：
文献类型：
--
作者：
Baidya, M.;Mayr, Herbert
测定了DBU和DBN对C（sp）（2）心的亲核性和刘易斯碱性：亲核性按DMAP < DBU < DBN < DABCO的顺序增加，而刘易斯碱性按DABCO < DMAP < DBU < DBN的顺序增加。
The nucleophilicity and Lewis basicity of DBU and DBN toward C(sp)(2) centers have been measured: nucleophilicities increase in the series DMAP < DBU < DBN < DABCO while Lewis basicities are DABCO < DMAP < DBU < DBN.