UNUSUAL DOUBLE SILYLATION REACTION OF A PTSI2P2 COMPLEX WITH AN O-CARBORANYL UNIT
UNUSUAL DOUBLE SILYLATION REACTION OF A PTSI2P2 COMPLEX WITH AN O-CARBORANYL UNIT
复制标题
PTSI2P2 配合物与 O-碳硼酰基单元的异常双硅烷化反应
作者：
Youngjin Kang;S. Kang;J. Ko
Pt(CH2CH2)(PPh3)2 和邻双(二甲基甲硅烷基)碳硼烷反应生成环状双(甲硅烷基)铂络合物 2。络合物 2 与多种底物如炔、二酮和腈反应，生成一类包含烯烃、酮酸酯、亚胺和胺的新型杂环化合物。
Reaction of Pt(CH2CH2)(PPh3)2 and o-bis(dimethylsilyl)carborane provides the cyclic bis(silyl)platinum complex 2. The complex 2 reacts with a variety of substrates such as an alkyne, dione, and nitrile, generating a new class of heterocyclic compounds incorporating an alkene, ketonate, imine, and amine.