Synthesis of the (9R,13R)-isomer of LDS1, a flower-inducing oxylipin isolated from Lemna paucicostata
Synthesis of the (9R,13R)-isomer of LDS1, a flower-inducing oxylipin isolated from Lemna paucicostata
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LDS1 的 (9R,13R)-异构体的合成，LDS1 是一种从 Lemna paucicostata 中分离出来的花诱导氧脂素
DOI：
10.1080/09168451.2016.1166935
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发表时间：
2016
期刊：
影响因子：
--
通讯作者：
Shigefumi Kuwahara,
中科院分区：
文献类型：
--
作者：
Yuki Takayasu;Yusuke Ogura;Ryo Towada;Shigefumi Kuwahara,
LDS1的（9R,13R）立体异构体是一种从lena paucicostata中分离出来的诱导花的氧脂素，已经从一种已知的烯丙醇中通过七个步骤合成完成，包括Horner-Wadsworth-Emmons烯烃化以构建其完整的碳框架，并酶解倒数第二甲基酯中间体以提供目标分子。
The first synthesis of the (9R,13R)-stereoisomer of LDS1, a flower-inducing oxylipin isolated fromLemna paucicostata, has been achieved from a known allylic alcohol by a seven-step sequence that involves the Horner–Wadsworth–Emmons olefination to construct its full carbon framework and an enzymatic hydrolysis of a penultimate methyl ester intermediate to provide the target molecule.