Reversible formation of regular pentagonal dodecahedral (H2O)20 in a 2D metal–organic framework

Reversible formation of regular pentagonal dodecahedral (H2O)20 in a 2D metal–organic framework
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DOI:
10.1039/b922161a
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发表时间:
2010-04
期刊:
影响因子:
3.1
通讯作者:
Ruili Sang;Li Xu
Ruili Sang;Li Xu
中科院分区:
化学3区
文献类型:
--
作者:
Ruili Sang;Li Xu

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The regular pentagonal (H2O)20 dodecahedra has been found in the cavity of 2D [Ag6(Pra2biim)3]. It consists of two two-coordinated, eight three-coordinated and ten four-coordinated oxygen atoms accompanied by 28 surface hydrogen bonds and 12 apical hydrogen bonds. The reversible formation of the (H2O)20 cluster has been reported for the first time.