Experimental Modeling of the Processes of Ozone Hydrate Clathrate Formation
Experimental Modeling of the Processes of Ozone Hydrate Clathrate Formation
复制标题
臭氧水合物笼形物形成过程的实验模拟
DOI：
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发表时间：
2008
期刊：
影响因子：
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通讯作者：
V. Lunin
中科院分区：
文献类型：
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作者：
T. A. Vysokikh;T. V. Yagodovskaya;S. Savilov;V. Lunin
摘要研究了近平流层条件下臭氧水合物的可能形成及其与氯化氢的相互作用。低温红外光谱技术被用来证明在77-220 K的温度范围内稳定的臭氧水合物的原位形成。结果表明，在220 K以上，HCl与臭氧水合物发生反应，破坏了笼形物。这一过程产生了不同组成的氯氧化物。
AbstractThe possible formation of ozone hydrates and their interaction with hydrogen chloride under near-stratospheric conditions were investigated. The low-temperature IR spectroscopic technique was used to demonstrate the in situ formation of ozone hydrates that were stable in the temperature range 77–220 K. It was found that HCl reacted with ozone hydrate to destruct clathrate at temperatures above 220 K. This process resulted in compositionally different chlorine oxides.