Redox Chemistry between Europium(III) Amide and Pyrrolyl-Functionalized Secondary Amines. Synthesis and Structural Characterization of Lithium and Novel Lanthanide Complexes Incorporating Functionalized Pyrrolyl Ligands

Redox Chemistry between Europium(III) Amide and Pyrrolyl-Functionalized Secondary Amines. Synthesis and Structural Characterization of Lithium and Novel Lanthanide Complexes Incorporating Functionalized Pyrrolyl Ligands
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铕(III)酰胺和吡咯基官能化仲胺之间的氧化还原化学。

DOI:
10.1021/om101043t
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发表时间:
2011-02
期刊:
影响因子:
2.8
通讯作者:
Rong, Jiewei
Rong, Jiewei
中科院分区:
化学2区
文献类型:
--
作者:
Zhang, Lijun;Zhu, Xiancui;Li, Qinghai;Wang, Fenhua;Yang, Song;Wang, Shaowu;Zhou, Shuangliu;Wei, Yun;Rong, Jiewei

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首次发现了酰胺铕[(Me 3Si)2N]3EuIII(μ-Cl)Li(THF)3与吡咯基仲胺的氧化还原反应。研究了2-(2,6-R_2C_6H_3NHCH_2)C_4H_3NH(R = CH_3(1),R = iPr(2))与2当量铕的相互作用
The redox reaction between the europium(III) amide [(Me3Si)2N]3EuIII(μ-Cl)Li(THF)3 and pyrrolyl-functionalized secondary amines was found for the first time. The interactions of 2-(2,6-R2C6H3NHCH2)C4H3NH (R = CH3 (1), R = iPr (2)) with 2 equiv of europium