The Facile Synthesis and Characterization of Novel Cationic Metallated and Nonmetallated Tetrapyridino Porphyrazines Having Different Metal Centers
The Facile Synthesis and Characterization of Novel Cationic Metallated and Nonmetallated Tetrapyridino Porphyrazines Having Different Metal Centers
复制标题
具有不同金属中心的新型阳离子金属化和非金属化四吡啶并紫菜嗪的简易合成和表征
DOI：
10.1081/scc-200030591
复制
发表时间：
2004
影响因子：
2.1
通讯作者：
R. Sheardy
中科院分区：
文献类型：
--
作者：
C. Ramirez;C. Antonacci;Jaime M. Ferreira;R. Sheardy
摘要合成了金属和非金属的一系列四阳离子卟嗪和一种新的卟嗪化合物。以45%的产率得到了中性的四联吡啶并卟嗪。以79%的产率合成了四阳离子非金属四乙醇四联吡啶碘化卟啉。金属卟啉为(Mn+2，Cu+2，Co+2，Zn+2)=M。以78%、69%、75%和72%的产率合成了四乙基吡啶四氮杂卟啉。用元素分析、ESI-MS、MALDI-MS、FTIR和UV-Vis对非金属化和金属化的卟嗪和四阳离子卟嗪进行了表征。
Abstract A porphyrazine and a series of tetracationic porphyrazines, metallated and nonmetallated, were synthesized. The neutral tetrapyridino porphyrazine was obtained in a yield of 45%. The tetracationic nonmetallated tetraethanoltetrapyridino porphyrazinium iodide was obtained in a yield of 79%. The metallated porphyrazines are (Mn+2, Cu+2, Co+2, Zn+2) = M. M‐Tetraethanoltetrapyridino porphyrazinium iodide was obtained in a yield of 78%, 69%, 75%, and 72%, respectively. The porphyrazine and the tetracationic porphyrazines, nonmetallated and metallated, were characterized by elemental analysis, ESI‐MS, MALDI‐MS, FTIR, and UV‐VIS.
影响因子：
2.9
作者：
Fedoroff, OY;Salazar, M;Hurley, LH
通讯作者：
Hurley, LH
影响因子：
2.9
作者：
Han, HY;Cliff, CL;Hurley, LH
通讯作者：
Hurley, LH
影响因子：
13.5
作者：
Hurley, LH;Wheelhouse, RT;Von Hoff, DD
通讯作者：
Von Hoff, DD