Tetraphenylantimony(V)-assisted transfer of hydroxide and fluoride anions across the 1,6-dichlorohexane | water interface
Tetraphenylantimony(V)-assisted transfer of hydroxide and fluoride anions across the 1,6-dichlorohexane | water interface
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四苯基锑 (V) 辅助氢氧根和氟阴离子穿过 1,6-二氯己烷的转移 |
DOI：
10.1007/s44211-022-00135-1
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发表时间：
2022
影响因子：
1.6
通讯作者：
Uematsu Kohei
中科院分区：
文献类型：
--
作者：
Katano Hajime;Sawazaki Yuto;Sakae Hiroki;Uematsu Kohei
在1，6-二氯己烷（DCH）上的离子转移反应|用伏安法研究了有机金属阳离子四苯锑（TPhSb+）在DCH中的水（W）界面。当TPhSb+盐与[（C4 F9 SO2）2N]-离子被加入到DCH-相中，W-相在pH < 6的缓冲液中时，由于TPhSb+离子在DCH中的简单转移，|在极化电位窗口内观察到W界面。当W相在pH > 7的缓冲液中时，中点电位随着pH的增加而向更正的电位移动。伏安图可以归因于通过形成TPhSbOH辅助的OH−离子的转移，TPhSbOH在DCH中是稳定的。此外，由于TPhSb+辅助F−离子的转移，在TPhSb+（DCH）处观察到7可逆伏安图。|F−（W，无缓冲）界面系统。当用TPhSbOH或TPhSbF代替DCH中的TPhSb[（C4 F9 SO2）2N]时，获得了相同的结果，表明TPhSb+和TPhSbOH（DCH）的适用性。|OH−（W）界面体系与碱性溶液pH传感器及TPhSb+和TPhSbF（DCH）的界面体系|F−（W）接口到F−离子传感器。图形摘要
The ion-transfer reaction at the 1,6-dichlorohexane (DCH) | water (W) interface in the presence of an organometallic cation, tetraphenylantimony (TPhSb+), in DCH was studied voltammetrically. When TPhSb+salt with [(C4F9SO2)2N]−ion was added to the DCH-phase and the W-phase was buffered at pH < 6, a reversible cyclic voltammogram due to the simple transfer of TPhSb+ion across the DCH | W interface was observed within the polarizable potential window. When the W-phase was buffered at pH > 7, the midpoint potential shifted to more positive potentials with increasing pH. The voltammogram could be attributed to the transfer of the OH−ion assisted by the formation of TPhSbOH, which is stable in DCH. Also, a 7reversible voltammogram due to the TPhSb+-assisted transfer of F−ion was observed at the TPhSb+(DCH) | F−(W, unbuffered) interfacial system. The same results were achieved when TPhSb[(C4F9SO2)2N] in DCH was replaced by TPhSbOH or TPhSbF, indicating the applicability of the TPhSb+and TPhSbOH (DCH) | OH−(W) interfacial system to a pH sensor for alkaline solution and that of the TPhSb+and TPhSbF (DCH) | F−(W) interface to a F−ion sensor.Graphical abstract
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影响因子：
1.6
作者：
Katano, H;Murayama, Y;Tatsumi, H
通讯作者：
Tatsumi, H
影响因子：
4
作者：
Nishizawa, S;Yokobori, T;Teramae, N
通讯作者：
Teramae, N
1,6-二氯己烷|水和1,4-二氯丁烷|水界面的离子转移伏安法。
影响因子：
6.1
作者：
H. Katano;Hirosuke Tatsumi;M. Senda
通讯作者：
M. Senda
氟溶剂1,1,1,2,3,4,4,5,5,5-十氟戊烷作为液-液电化学非水介质的适用性
DOI：
--
发表时间：
2017
期刊：
影响因子：
--
作者：
H. Katano;Yasuhiro Kuroda;Kohei Uematsu
通讯作者：
Kohei Uematsu