Photochemical Reduction of CO2 with Red Light Using Synthetic Chlorophyll-Rhenium Bipyridine Dyad

Photochemical Reduction of CO2 with Red Light Using Synthetic Chlorophyll-Rhenium Bipyridine Dyad
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DOI:
10.1246/cl.140439
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发表时间:
2014-08-05
期刊:
影响因子:
1.6
通讯作者:
Tamiaki, Hitoshi
Tamiaki, Hitoshi
中科院分区:
化学4区
文献类型:
--
作者:
Kitagawa, Yuichi;Takeda, Hiroyuki;Tamiaki, Hitoshi

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我们成功地进行了还原CO2 CO的选择性照明的红色可见光的叶绿素衍生物共价连接的一个cubipyridine复合物。这是使用在超过650 nm的波长处具有强吸收的敏化剂的CO2的光化学还原的第一个实例。
We successfully performed the reduction of CO2 to CO by selective illumination of red visible light to a chlorophyll derivative covalently linked with a rhenium bipyridine complex. This is the first example of the photochemical reduction of CO2 using a sensitizer that has strong absorption at a wavelength over 650 nm.