A novel dodecanuclear chromium(III) cage: structural control by choice of leaving group
A novel dodecanuclear chromium(III) cage: structural control by choice of leaving group
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DOI：
10.1039/b001140l
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发表时间：
2000
影响因子：
4.9
通讯作者：
S. Parsons;Andrew A. Smith;R. Winpenny
中科院分区：
文献类型：
--
作者：
S. Parsons;Andrew A. Smith;R. Winpenny
报道了一种新型金属多面体的合成和结构表征，涉及铬（III）和异丁酸盐;将该产品与使用不同羧酸盐获得的产品进行比较表明，离去基团（可以是羧酸盐、水或两者）强烈影响所发现的结构。
The synthesis and structural characterisation of a novel metal polyhedron is reported, involving chromium(III) and isobutyrate; comparison of this product with those obtained using different carboxylates suggests that the leaving group—which can be carboxylate, water or both—strongly influences the structure found.