Fabrication of Ce doped UiO-66/graphene nanocomposites with enhanced visible light driven photoactivity for reduction of nitroaromatic compounds

Fabrication of Ce doped UiO-66/graphene nanocomposites with enhanced visible light driven photoactivity for reduction of nitroaromatic compounds
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制备具有增强可见光驱动光活性的 Ce 掺杂 UiO-66/石墨烯纳米复合材料,用于还原硝基芳香族化合物

DOI:
10.1016/j.apsusc.2017.05.158
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发表时间:
2017-10
影响因子:
6.7
通讯作者:
Lei Ziqiang
Lei Ziqiang
中科院分区:
材料科学1区
文献类型:
--
作者:
Yang Zhiwang;Xu Xueqing;Liang Xixi;Lei Cheng;Gao Lihong;Hao Ruoxue;Lu Dedai;Lei Ziqiang

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This study investigates the photocatalytic reduction of nitroaromatic compounds upon visible light over novel Ce-doped UiO-66/graphene nanocomposites. Ce doped UiO-66 nanostructures and the corresponding graphene hybridized nanocomposites were facilely synthesized by means of one step solvothermal reaction. It has been demonstrated that produced nanocomposites could be used as highly efficient and chemical stable photocatalysts for the reduction of nitroaromatic compounds under visible irradiation and ambient conditions. Compared with the bare UiO-66, Ce-UiO-66/GR distinctly enhanced photocatalytic activity. Ce as“mediator”introduced into the MOFs materials can greatly improve the electron transfer across the interface between grephene and the UiO-66 and further improve the visible light driven photoactivity. This is an effective strategy for the development of high photocatalytic activity MOFs based materials.
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