A promising synergistic effect of nickel ferrite loaded on the layered double hydroxide-derived carrier for enhanced photocatalytic hydrogen evolution
A promising synergistic effect of nickel ferrite loaded on the layered double hydroxide-derived carrier for enhanced photocatalytic hydrogen evolution
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铁酸镍负载在层状双氢氧化物衍生载体上具有良好的协同效应,可增强光催化析氢
DOI:
10.1016/j.ijhydene.2016.10.018
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发表时间:
2017-01
影响因子:
7.2
通讯作者:
Zhi-Ping Xu
中科院分区:
文献类型:
--
作者:
Wei-De Wang;Guang-Ren Qian;Yong-Gang Jin;Zhi-Ping Xu
In this study, an attempt was made to modify the photocatalytic properties of an ion-exchangeable semiconductor material to enhance the efficiency of hydrogen production. Visible-light active NiFe2O4was loaded onto Nisingle bondZn/Cr layered double hydroxide (LDH) (Ni/Zn molar ratio = 75/25) with the Fe/Cr molar ratio of 0.005, 0.010, and 0.015 as cocatalyst through a simple solvothermal process and subsequently subjected to calcination at temperature of 500 °C. The results revealed that the presence of the loaded cocatalyst significantly facilitated the photocatalytic activity and the mixed oxide with Fe/Cr = 0.010 displayed the highest photocatalytic activity for visible light-induced H2generation. The optimal amount of hydrogen evolution reached to 269.44 μmolh−1under visible light (λ > 420 nm), which is far superior to that of the pristine Nisingle bondZn/Cr LDH-derived oxides material (130.85 μmolh−1), indicating the important catalytic role of NiFe2O4. The significant enhancement in photoactivity was attributed to the synergistic effect of nickel ferrite attached on the external surface of the calcined brucite-like sheets of the LDH. The cocatalyst NiFe2O4nanoparticles increase the donor or acceptor levels in comparison with the pristine Nisingle bondZn/Cr LDH-derived semiconductor oxide. Moreover, the existence of sheet-like LDH-derived carrier could inhibit the rapid recombination of photogenerated electrons and holes.
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影响因子:
13.6
作者:
Yao, Yunjin;Cai, Yunmu;Wang, Shaobin
通讯作者:
Wang, Shaobin
DOI:
10.1039/c2cp43628k
发表时间:
2013-07
期刊:
Physical chemistry chemical physics : PCCP
影响因子:
--
作者:
Wenguang Wang;Shengwei Liu;L. Nie;B. Cheng;Jiaguo Yu
通讯作者:
Wenguang Wang;Shengwei Liu;L. Nie;B. Cheng;Jiaguo Yu
影响因子:
5.2
作者:
E. Seftel;E. Popovici;M. Mertens;K. Witte;G. Tendeloo;P. Cool;E. Vansant
通讯作者:
E. Seftel;E. Popovici;M. Mertens;K. Witte;G. Tendeloo;P. Cool;E. Vansant
影响因子:
15
作者:
Gunjakar, Jayavant L.;Kim, Tae Woo;Hwang, Seong-Ju
通讯作者:
Hwang, Seong-Ju
影响因子:
3.3
作者:
Xiao, Yinglin;Zai, Jiantao;Qian, Xuefeng
通讯作者:
Qian, Xuefeng