A promising synergistic effect of nickel ferrite loaded on the layered double hydroxide-derived carrier for enhanced photocatalytic hydrogen evolution

A promising synergistic effect of nickel ferrite loaded on the layered double hydroxide-derived carrier for enhanced photocatalytic hydrogen evolution
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铁酸镍负载在层状双氢氧化物衍生载体上具有良好的协同效应,可增强光催化析氢

DOI:
10.1016/j.ijhydene.2016.10.018
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发表时间:
2017-01
影响因子:
7.2
通讯作者:
Zhi-Ping Xu
Zhi-Ping Xu
中科院分区:
工程技术2区
文献类型:
--
作者:
Wei-De Wang;Guang-Ren Qian;Yong-Gang Jin;Zhi-Ping Xu

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In this study, an attempt was made to modify the photocatalytic properties of an ion-exchangeable semiconductor material to enhance the efficiency of hydrogen production. Visible-light active NiFe2O4was loaded onto Nisingle bondZn/Cr layered double hydroxide (LDH) (Ni/Zn molar ratio = 75/25) with the Fe/Cr molar ratio of 0.005, 0.010, and 0.015 as cocatalyst through a simple solvothermal process and subsequently subjected to calcination at temperature of 500 °C. The results revealed that the presence of the loaded cocatalyst significantly facilitated the photocatalytic activity and the mixed oxide with Fe/Cr = 0.010 displayed the highest photocatalytic activity for visible light-induced H2generation. The optimal amount of hydrogen evolution reached to 269.44 μmolh−1under visible light (λ > 420 nm), which is far superior to that of the pristine Nisingle bondZn/Cr LDH-derived oxides material (130.85 μmolh−1), indicating the important catalytic role of NiFe2O4. The significant enhancement in photoactivity was attributed to the synergistic effect of nickel ferrite attached on the external surface of the calcined brucite-like sheets of the LDH. The cocatalyst NiFe2O4nanoparticles increase the donor or acceptor levels in comparison with the pristine Nisingle bondZn/Cr LDH-derived semiconductor oxide. Moreover, the existence of sheet-like LDH-derived carrier could inhibit the rapid recombination of photogenerated electrons and holes.
磁性可回收MnFe2O4和MnFe2O4-石墨烯杂化物作为过一硫酸盐活化的多相催化剂,用于有效降解水性有机污染物
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期刊: Physical chemistry chemical physics : PCCP
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