The reaction of acetylenes with compounds containing Fe–Aryl bonds. A convenient and novel synthesis of indenones
The reaction of acetylenes with compounds containing Fe–Aryl bonds. A convenient and novel synthesis of indenones
复制标题
乙炔与含有 Fe-芳基键的化合物的反应一种方便且新颖的茚酮合成方法。
DOI：
10.1039/c39870000439
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发表时间：
1987
期刊：
影响因子：
--
通讯作者：
S. Rettig
中科院分区：
文献类型：
--
作者：
I. Butler;W. Cullen;W. Lindsell;P. Preston;S. Rettig
二苯基乙炔与(η5-C5H5)Fe(CO)2Ar(3)反应生成吲哚(4)和(5)，当乙炔为2-乙炔基吡啶时，得到环己二烯-亚甲基衍生物(10)，其结构经X-射线晶体分析确定。
The reaction of diphenylacetylene with (η5-C5H5)Fe(CO)2Ar (3) affords the indenones (4) and/or (5); a cyclohexadienyliron derivative (10) is obtained when the acetylene is 2-ethynylpyridine, the structure of which was determined by X-ray crystallography.