Indium-mediated propargylation of aldehydes: regioselectivity and enantioselectivity studies

Indium-mediated propargylation of aldehydes: regioselectivity and enantioselectivity studies
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DOI:
10.1016/s0040-4039(02)02613-8
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发表时间:
2003-01-13
影响因子:
1.8
通讯作者:
Tan, KL
Tan, KL
中科院分区:
化学4区
文献类型:
--
作者:
Loh, TP;Lin, MJ;Tan, KL

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在有机溶剂中,以化学计量的(-)-辛可尼定为手性源,实现了醛的炔丙基化反应,对映选择性高达85%。(C)2002爱思唯尔科技有限公司。保留所有权利。
An enantioselective propargylation reaction of aldehydes with enantioselectivity up to 85% has been achieved in organic solvents by using stoichiometric amounts of (-)-cinchonidine as the chiral source. (C) 2002 Elsevier Science Ltd. All rights reserved.