A pulse radiolysis study of I and (SCN) in aqueous solutions over the temperature range 15–90°C
A pulse radiolysis study of I and (SCN) in aqueous solutions over the temperature range 15–90°C
复制标题
15–90°C 温度范围内水溶液中 I 和 (SCN) 的脉冲辐射分解研究
DOI：
10.1002/kin.550161007
复制
发表时间：
1984
影响因子：
1.5
通讯作者：
F. Sopchyshyn
中科院分区：
文献类型：
--
作者：
A. Elliot;F. Sopchyshyn
在15- 90 ℃温度范围内测定了I_2和（SCN）_2的消光系数和衰减动力学。基于（SCN）2在475 nm处的消光系数等于7600 M cm，测定I2在385和725 nm处的消光系数分别为10，000和2560 M cm。在这三个波长处，所有消光系数在所研究的温度范围内是恒定的。I2和（SCN）2的衰减速率被发现是一个函数的I和SCN的浓度，以及温度。参考文献28篇，附图5幅。
The extinction coefficients and the decay kinetics of I2 and (SCN)2 have been characterized over the 15-90C-temperature range. The extinction coefficients of I2 at 385 and 725 nm were determined to be 10,000 and 2560M cm , respectively, based on the extinction coefficient of (SCN)2 at 475 nm being equal to 7600M cm . At these three wavelengths, all extinction coefficients were constant over the temperature range studied. The rate of decay of both I2 and (SCN)2 was found to be a function of I and SCN concentration, respectively, as well as temperature. 28 references, 5 figures.