23-Electron Octahedral Molybdenum Cluster Complex [{Mo 6 I 8 }Cl 6 ] -
23-Electron Octahedral Molybdenum Cluster Complex [{Mo 6 I 8 }Cl 6 ] -
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23-电子八面体钼簇合物 [{Mo 6 I 8 }Cl 6 ] -
DOI：
10.1021/acs.inorgchem.7b02760
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发表时间：
2017
影响因子：
4.6
通讯作者：
Vorotnikova N
中科院分区：
文献类型：
--
作者：
Vorotnikova N
易于发生可逆氧化还原反应的光活性过渡金属化合物对于包括催化、光电子学和传感在内的无数应用是重要的。本文介绍了用化学和电化学方法制备簇合物（Bu_4N）[{Mo_6I_8} Cl_6]的方法，该簇合物是钼、钨和铼的八面体簇合物家族中一种罕见的23电子簇合物。低温和室温下的晶体结构，电子结构，和磁，光学和电化学性质的这种复杂的描述。
Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e–cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.