Porous zinc(II) frameworks with 5-(isonicotinamido)isophthalate: Syntheses, structures and properties
Porous zinc(II) frameworks with 5-(isonicotinamido)isophthalate: Syntheses, structures and properties
复制标题
具有 5-(异烟酰胺基)间苯二甲酸酯的多孔锌 (II) 骨架：合成、结构和性能
DOI：
10.1016/j.micromeso.2010.10.011
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发表时间：
2011-03-01
影响因子：
5.2
通讯作者：
Ueyama, Norikazu
中科院分区：
文献类型：
--
作者：
Chen, Man-Sheng;Chen, Min;Ueyama, Norikazu
在N，N-二甲基甲酰胺（DMF）和N，N-二乙基甲酰胺（DEF）中，Zn（NO3）（2）中心点6 H（2）O分别与5-（异烟酰胺基）烟酸（H（2）INAIP）反应，合成了两种新的三维配位聚合物[Zn（INAIP）]中心点2DMF（1）和[Zn（INAIP）]中心点9 H（2）O（2）.溶剂的变化导致形成不同结构、拓扑结构以及不同孔径和形状的中性骨架。X射线晶体结构分析表明，配合物1是一种罕见的三维结构，具有（3，6）-连接的金红石（rtl）拓扑结构，包含二维（2D）（4，4）网络，而配合物2的三维骨架具有（3，6）-连接的（4（2）.6）（2）（4（4）.6（2）.8（6）.10（3））拓扑结构，具有二维kagome层。研究了配合物的稳定性、发光性能和吸附性能。(c)2010年爱思唯尔公司All rights reserved.
Two new three-dimensional (3D) coordination polymers [Zn(INAIP)]center dot 2DMF (1) and [Zn(INAIP)]center dot 9H(2)O (2) have been synthesized by reactions of Zn(NO3)(2)center dot 6H(2)O with 5-(isonicotinamido)isophthalic acid (H(2)INAIP) in N,N-dimethylformamide (DMF) and N,N-diethylformamide (DEF), respectively. The change of solvent leads to the formation of neutral frameworks with different structure, topology as well as different pore size and shape. The X-ray crystallographic structural analysis revealed that complex 1 is an unusual 3D architecture with (3, 6)-connected rutile (rtl) topology containing two-dimensional (2D) (4, 4) networks, while the 3D framework in 2 has (3, 6)-connected (4(2).6)(2)(4(4).6(2).8(6).10(3)) topology with 2D kagome layers. In addition, the stabilities, luminescence and adsorption properties of the complexes were investigated. (c) 2010 Elsevier Inc. All rights reserved.