Light-Driven Carboxylation of o-Alkylphenyl Ketones with CO2

Light-Driven Carboxylation of o-Alkylphenyl Ketones with CO2
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DOI:
10.1021/jacs.5b10032
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发表时间:
2015-11-11
影响因子:
15
通讯作者:
Murakami, Masahiro
Murakami, Masahiro
中科院分区:
化学1区
文献类型:
--
作者:
Masuda, Yusuke;Ishida, Naoki;Murakami, Masahiro

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O-烷基苯基酮在紫外光甚至太阳光的照射下,与二氧化碳发生C-C键的羧化反应。该反应是一种清洁的过程,利用光能作为有机分子与二氧化碳羧化的驱动力。
o-Alkylphenyl ketones undergo a C-C bond forming carboxylation reaction with CO2 simply upon irradiation with UV light or even solar light. The reaction presents a clean process exploiting light energy as the driving force for carboxylation of organic molecules with CO2.